Influence of solvent on cyclic polynorbornene tacticity
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Updated: Jul 11, 2025

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
Published on: February 27, 2017
Sung-Min Hyun1, Arkadios Marathianos2, Parker T Boeck1,3
1University of Florida, Department of Chemistry, Center for Catalysis, P.O. Box 117200, Gainesville, FL, 32611, USA. veige@chem.ufl.edu.
Abstract:
Tacticity is critical to polymer properties. The influence of solvent on tacticity in the catalytic synthesis of cyclic polynorbornene (c-PNB) is reported. In toluene cis,syndiotactic c-PNB forms; in THF, cis,syn/iso c-PNB forms.
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