Fixed-bed column adsorption modeling using Zr biocomposites for fluoride removal

This research involved conducting continuous adsorption experiments to assess fluoride elimination from drinking water achieved by utilizing biocomposites created from the peels of oranges and apples, which were impregnated with zirconium (Zr), to form BOP-Zr and BAP-Zr, respectively. The findings from the experimental data indicate that BOP-Zr and BAP-Zr are effective biosorbents with a solid ability to remove fluoride selectively. Additionally, these biosorbents were found to be stable, as they do not release Zr into the treated water. Notably, these environmentally friendly biosorbents are derived from renewable sources and enhance the value of waste materials. The study employed various empirical models, including Bohart-Adamas, Thomas, Yoon-Nelson, BDST, Clark, Yan, and Woolborska, to elucidate the mechanisms and crucial parameters involved in fluoride adsorption within packed bed columns. The Yan model demonstrated the highest correlation among these models, indicating a chemical adsorption process with kinetics following a pseudo-second-order pattern. BOP-Zr and BAP-Zr exhibited a maximum adsorption capacity of 59.3 and 47.5 mg/g, respectively, under a flow rate of 4 mL/min and an inlet fluoride concentration of 25 mg/L. The analysis of mass transfer coefficients revealed that the primary step governing the adsorption procedure was diffusion through pores. Consequently, the study conclusively establishes that BOP-Zr and BAP-Zr biocomposites, originating from lignocellulosic biomass remains, present a practical and competitive choice for eliminating fluoride from water. These materials surpass waste materials in performance and rival more expensive options in efficiency and performance.