Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

42.7K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
42.7K
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

26.6K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
26.6K
π Electron Effects on Chemical Shift: Overview01:27

π Electron Effects on Chemical Shift: Overview

1.1K
An applied magnetic field causes loosely bound π-electrons in organic molecules to circulate, producing a local or induced diamagnetic field over a large spatial volume. As the molecules tumble in solution, the field generated by π-electrons in spherical substituents results in a zero net field. However, the net field generated by π-electrons in non-spherical substituents is not zero. The effect of this induced field depends on the orientation of the molecule with respect to B0,...
1.1K
Valence Bond Theory02:42

Valence Bond Theory

8.6K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
8.6K
Colors and Magnetism03:02

Colors and Magnetism

11.7K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.7K
Chirality at Nitrogen, Phosphorus, and Sulfur02:30

Chirality at Nitrogen, Phosphorus, and Sulfur

5.7K
Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
5.7K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Line Width-Activated Interband Contribution to Thermally Driven Phonon Angular Momentum.

Nano letters·2026
Same author

Graphene-Mediated Contact Engineering for a High Thermoelectric Performance in 2D PdSe<sub>2</sub>.

ACS applied materials & interfaces·2026
Same author

Modulating Thermal Conductivity via Targeted Phonon Excitation.

Nano letters·2024
Same author

Chiral Phonons: Prediction, Verification, and Application.

Nano letters·2024
Same author

Low voltage-driven high-performance thermal switching in antiferroelectric PbZrO<sub>3</sub> thin films.

Science (New York, N.Y.)·2023
Same author

Chiral-phonon-activated spin Seebeck effect.

Nature materials·2023

Related Experiment Video

Updated: Jul 11, 2025

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
09:06

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope

Published on: March 24, 2019

8.1K

Phonon Chirality Manipulation Mechanism in Transition-Metal Dichalcogenide Interlayer-Sliding Ferroelectrics.

Hao Chen1,2, Qianqian Wang3, Xukun Feng3

  • 1Department of Physics, University of Science and Technology of China, Hefei 230026, China.

Nano Letters
|November 17, 2023
PubMed
Summary

Researchers manipulated chiral phonons in transition-metal dichalcogenide materials using a sliding ferroelectric effect. This breakthrough offers new control over phonon chirality, impacting future studies and applications.

Keywords:
first-principles calculationsinterlayer-sliding ferroelectricsphonon Berry curvaturephonon Hall effectphonon chirality manipulationtransition-metal dichalcogenide materials

More Related Videos

Fabricating van der Waals Heterostructures with Precise Rotational Alignment
09:25

Fabricating van der Waals Heterostructures with Precise Rotational Alignment

Published on: July 5, 2019

9.5K
Ohmic Contact Fabrication Using a Focused-ion Beam Technique and Electrical Characterization for Layer Semiconductor Nanostructures
08:12

Ohmic Contact Fabrication Using a Focused-ion Beam Technique and Electrical Characterization for Layer Semiconductor Nanostructures

Published on: December 5, 2015

12.4K

Related Experiment Videos

Last Updated: Jul 11, 2025

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
09:06

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope

Published on: March 24, 2019

8.1K
Fabricating van der Waals Heterostructures with Precise Rotational Alignment
09:25

Fabricating van der Waals Heterostructures with Precise Rotational Alignment

Published on: July 5, 2019

9.5K
Ohmic Contact Fabrication Using a Focused-ion Beam Technique and Electrical Characterization for Layer Semiconductor Nanostructures
08:12

Ohmic Contact Fabrication Using a Focused-ion Beam Technique and Electrical Characterization for Layer Semiconductor Nanostructures

Published on: December 5, 2015

12.4K

Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Phononics

Background:

  • Chiral phonons, crucial for novel electronic and spintronic applications, were theoretically predicted and experimentally verified in transition-metal dichalcogenide (TMD) materials.
  • The manipulation of phonon chirality in TMDs is essential for advancing the study and application of these quasiparticles.

Purpose of the Study:

  • To investigate the sliding ferroelectric effect as a mechanism for manipulating phonon chirality in TMDs.
  • To explore the influence of interlayer sliding on phonon chirality and Berry curvature in bilayer and multilayer MoS2.

Main Methods:

  • First-principles calculations were employed to study the effects of interlayer sliding.
  • Analysis focused on bilayer and four-layer MoS2 exhibiting sliding ferroelectricity.

Main Results:

  • Interlayer sliding demonstrated distinct effects on phonon chirality and Berry curvature in bilayer versus four-layer MoS2.
  • Phonon angular momentum, magnetization under temperature gradients, and the phonon Hall effect under magnetic fields were shown to be influenced by this manipulation.
  • The study establishes a connection between ferroelectricity and phonon chirality control in TMDs.

Conclusions:

  • The sliding ferroelectric effect provides a novel mechanism for manipulating phonon chirality in transition-metal dichalcogenide materials.
  • This research opens new avenues for controlling phonon properties and exploring their interactions with other physical phenomena.