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Updated: Jul 10, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
1D/2D core-shell structure Ni-Mo-S@NiFe LDH grown on nickel foam: a bifunctional electrocatalyst for efficient oxygen
Tengfei Zhang1, Dan Xu1, Ping Liu1
1School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832003, China. wanggang@shzu.edu.cn.
Abstract:
The construction of bifunctional catalysts for the oxygen evolution reaction (OER) and urea oxidation reaction (UOR) is important for accelerating the development of the hydrogen economy. Herein, a novel three-dimensional core-shell heterostructure (Ni-Mo-S@NiFeLDH/NF) was prepared by vertically growing NiFe layered double hydroxide (NiFe LDH) nanosheets on nickel foam (NF)-supported arrays of Ni-Mo-S (Ni3S2, Ni0.96S, Mo2S3) nanorods via a hydrothermal-sulfide-hydrothermal process. Benefiting from the unique core-shell structure with numerous exposed active sites, the optimized Ni-Mo-S@NiFe LDH/NF shows excellent OER/UOR activity, with an overpotential of only 274 mV for OER to reach 100 mA cm-2 and 1.318 V for UOR to reach 10 mA cm-2. Moreover, the assembled Ni-Mo-S@NiFe LDH||Pt/C urea electrolytic system requires only 1.348 V to achieve 10 mA cm-2, as much as 159 mV lower than pure water electrolysis. This work provides an idea for researching NiFe LDH-based OER/UOR bifunctional catalysts.
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