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Updated: Jul 9, 2025

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Chiral metal-organic cages decorated with binaphthalene moieties
Cheng Huang1,2, Jiajia Li1,3, Xinyuan Zhu1
1School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, China. wyfown@sjtu.edu.cn.
Abstract:
The construction of chiral nanoobjects with atomically precise nanostructures has attracted much more attention in the past decades. However, this field is still in its early stages. We designed and synthesized a series of chiral ligands containing the binaphthalene moiety and isophthalate module. Then, four chiral metal-organic cages (MOCs) were obtained through the coordination between isophthalate modules and copper ions. These chiral MOCs exhibit discrete, uniform and stable structures, good solubility and photoluminescence behaviors.
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