Enhanced safety and strength of cotton fabrics through a novel 'H-shaped' multiple flame retardant elements agent

In response to the new concept of green sustainability, it is necessary to expand the functionality of bio-based natural fibers (such as cotton fabrics) to replace fabrics made from fossil fuels. One potential way of achieving this is through the use of phosphorus, boron and nitrogen based organic flame retardants. This article designs a special flame retardant system with high efficiency, high durability, and enhanced fabric strength. An "H" shaped flame retardant (TBSA) is synthesized using hydroxyethyl methylene phosphate, pentaerythritol diborate, and cyanuric chloride. After simple treatment, flame retardant fabric (TBSA/Cotton) is obtained, with a LOI value of 48.8 %. Self extinguishing is completing in the vertical flame test. The high FR efficiency reflects the progressiveness of multi flame retardant elements. It is worth noting that TBSA/Cotton exhibits excellent durability and improves the strength of the fabric. This is attributed to the covalent bonding between the "H" type flame retardant and multiple cellulose molecules, which compensates for the cracks and holes at the submicroscopic scale of natural cellulose and weakens the molecular slip effect. The research results of this article provide a good opportunity for the development of biomass cellulose flame retardant materials.