Related Experiment Video
Updated: Jul 16, 2026
Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
The high-efficiency coupling of a Ni2+ coordinated/uncoordinated pyridine N-COF self-supporting nanofilm as an
Jia Zhang1, Zihao Zhang1, Xuteng Xing1
1College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China. xtxing@hebust.edu.cn.
Abstract:
A large-area COFTAPB-BPY film with a pore size of 3.9 nm was prepared on a gas-liquid interface by the virtue of the limiting and guiding functions of sodium dodecylbenzene sulfonate, followed by modification by Ni2+ ions with the reversible redox reaction of Ni(II/III), where Ni2+ was evidently anchored on the N in BPY. The obtained COFTAPB-BPY and Ni-COFTAPB-BPY nanofilms could avoid the inevitable aggregation and stacking of bulk COFTAPB-BPY, which facilitated a high specific capacitance of 0.26 mF cm-2 for the COFTAPB-BPY nanofilm and 0.38 mF cm-2 for the Ni-COFTAPB-BPY nanofilm at 0.001 mA cm-2. Considering the pseudocapacitance and double-layer capacitance traits of Ni-COFTAPB-BPY and COFTAPB-BPY nanofilms, the asymmetric Ni-COFTAPB-BPY//COFTAPB-BPY film supercapacitor was assembled with a symmetric COFTAPB-BPY//COFTAPB-BPY film device as a control. The asymmetric Ni-COFTAPB-BPY//COFTAPB-BPY film supercapacitor could enhance the energy density of 273.9 mW h cm-3 at 14.09 W cm-3 from 85.2 mW h cm-3 at 4.38 W cm-3 for the symmetric COFTAPB-BPY//COFTAPB-BPY film device. This work provides a new perspective on the application of self-supporting COF nanofilms as film asymmetric supercapacitors.
More Related Videos
12:00Evaluating the Electrochemical Properties of Supercapacitors using the Three-Electrode System
Published on: January 7, 2022
08:59Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
Published on: November 30, 2022
Related Concept Videos
01:12Energy Stored in a Capacitor
01:18Capacitor With A Dielectric
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
01:10Energy Stored in Capacitors
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...