Related Experiment Video
Updated: Jul 9, 2025

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
Published on: July 19, 2019
Effect of β-Substitution and β,β'-Fusion on the Formation of Boron Complexes of Porphycenes
Sameeta Sahoo1, Sipra Sucharita Sahoo1, Jodukathula Nagamaiah1
1School of Chemistry, University of Hyderabad, Hyderabad 500046, India.
Abstract:
Boron(III) complexation was investigated in a series of β-substituted porphycenes. Unlike meso-arylporphycenes, these macrocycles undergo a facile complexation reaction. Upon fusion of the β,β'-positions of the porphycene ligand, the complexation resulted in fast insertion of boron, forming the cisoid-B2OF2 complex. However, in the case of the other β-substituted porphycenes, only bis-BF2 complexes formed. The effect of these substituents on the core geometry and photophysical properties are elaborated here.
More Related Videos
08:56Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
Published on: November 30, 2022
19:58Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Related Concept Videos
Hydroboration-Oxidation of Alkenes
Regioselectivity and Stereochemistry of Hydroboration
Hydroboration proceeds in a concerted fashion with the attack of borane on the π bond, giving a cyclic four-centered transition state. The –BH2 group is bonded to the less substituted carbon and –H to the more substituted carbon. The concerted nature requires the simultaneous addition of –H and –BH2 across the same face of the alkene giving syn...
Hybridization of Atomic Orbitals I
Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
Electrophilic Aromatic Substitution: Fluorination and Iodination of Benzene
Radical Substitution: Allylic Bromination