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Updated: Jul 16, 2026

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A bipyrrole scaffold as an emerging Frontier in robust design of high energy materials
V Shanmugapriya1, Pradeepta K Panda1
1School of Chemistry, University of Hyderabad, Hyderabad 500 046, India. pradeepta.panda@uohyd.ac.in.
Abstract:
α,α'-Bipyrrole is employed for the first time towards the synthesis of polynitrated high-energy materials. An efficient and scalable 3-step route led to the fully nitrated hexanitro-N,N'-dimethylbipyrrole (HNDMBP). Its twisted and tightly packed framework combines density with resilience, delivering good energetic performance (8.02 km s-1, 28.2 GPa) alongside remarkable safety (IS: 40 J; FS: 240 N) and stability (∼300 °C). HNDMBP stands out as a powerful and safe platform for advanced energetic applications.
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