Superior capacity and easy separation of zirconium functionalized chitosan melamine foam for antimony(III/V) removal

Nowadays, highly toxic antimony has severely posed threat to water sources and jeopardized human health. Fabricating adsorbents with the capability of easy separation, high efficiency and large adsorption capacity remains a major challenge. In this paper, zirconium functionalized chitosan melamine foam (ZCMF) was fabricated with zirconium and chitosan crosslinked onto melamine foam, then utilized for the removal of antimony(III/V) in water. The characterization of SEM and EDS collectively showed that ZCMF has a porous structure which could boost the mass transfer rate and zirconium ions on the surface could provide plentiful active adsorption sites. Systematic adsorption experiments demonstrated that the experimental data of Sb(III) and Sb(V) were consistent with the pseudo-second-order and Elovich kinetic models, respectively, and the Langmuir maximum adsorption capacities were separately 255.35 mg g^-1 (Sb(III)) and 414.41 mg g^-1 (Sb(V)), which displayed prominent performance among adsorbents derived from biomass. Combining the XPS and FTIR characterization with experimental data, it is rational to speculate that ZCMF could remove Sb from aqueous solution through ligand exchange, electrostatic attraction, and surface complexation mechanisms. ZCMF exhibited excellent performance, including large adsorption capacity, easy separation, facile preparation and eco-friendliness. It could be a promising new adsorbent for the treatment of antimony-containing wastewater.