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Photocatalytic Conversion of Diluted CO2 into Tunable Syngas via Modulating Transition Metal Hydroxides
Kang-Qiang Lu1, Jin-Ge Hao1, Yu Wei1
1Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, College of Materials, Metallurgical and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China.
Abstract:
The conversion of diluted CO2 into tunable syngas via photocatalysis is critical for implementing CO2 reduction practically, although the efficiency remains low. Herein, we report the use of graphene-modified transition metal hydroxides, namely, NiCo1--GR, for the conversion of diluted CO2 into syngas with adjustable CO/H2 ratios, utilizing Ru dyes as photosensitizers. The Ni(OH)2-GR cocatalyst can generate 12526 μmol g-1 h-1 of CO and 844 μmol g-1 h-1 of H2, while the Co(OH)2-GR sample presents a generation rate of 2953 μmol g-1 h-1 for CO and 10027 μmol g-1 h-1 for H2. Notably, by simply altering the addition amounts of nickel and cobalt in the transition metal composite, the CO/H2 ratios in syngas can be easily regulated from 18:1 to 1:4. Experimental characterization of composites and DFT calculations suggest that the differing adsorption affinities of CO2 and H2O over Ni(OH)2-GR and Co(OH)2-GR play a significant role in determining the selectivity of CO and H2 products, ultimately affecting the CO/H2 ratios in syngas. Overall, these findings demonstrate the potential of graphene-modified transition metal hydroxides as efficient photocatalysts for CO2 reduction and syngas production.
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