Cu@Co with Dilatation Strain for High-Performance Electrocatalytic Reduction of Low-Concentration Nitric Oxide

Electrocatalytic reduction of nitric oxide (NO) to ammonia (NH₃ ) is a clean and sustainable strategy to simultaneously remove NO and synthesize NH₃ . However, the conversion of low concentration NO to NH₃ is still a huge challenge. In this work, the dilatation strain between Cu and Co interface over Cu@Co catalyst is built up and investigated for electroreduction of low concentration NO (volume ratio of 1%) to NH₃ . The catalyst shows a high NH₃ yield of 627.20 µg h^-1 cm^-2 and a Faradaic efficiency of 76.54%. Through the combination of spherical aberration-corrected transmission electron microscopy and geometric phase analyses, it shows that Co atoms occupy Cu lattice sites to form dilatation strain in the xy direction within Co region. Further density functional theory calculations and NO temperature-programmed desorption (NO-TPD) results show that the surface dilatation strain on Cu@Co is helpful to enhance the NO adsorption and reduce energy barrier of the rate-determining step (*NO to *NOH), thereby accelerating the catalytic reaction. To simultaneously realize NO exhaust gas removal, NH₃ green synthesis, and electricity output, a Zn-NO battery with Cu@Co cathode is assembled with a power density of 3.08 mW cm^-2 and an NH₃ yield of 273.37 µg h^-1 cm^-2 .