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Updated: Jul 6, 2025

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
CB4Se5: a planar tetracoordinate carbon CB4 core stabilized by peripheral Se/Se2 bridges
Li-Xia Bai1, Rui Sun1, Yan-Bo Wu1
1Nanocluster Laboratory, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China. guojc@sxu.edu.cn.
Abstract:
Replacing one of the peripheral Se with a Se2 bridge is an effective strategy to flatten the C4v CB4Se4 cluster. The global minimum of CB4Se5 contains one fan-shaped planar tetracoordinate carbon (ptC) CB4 core, possessing double 2π + 6σ aromaticity. The peripheral Se2 bridge is dexterous and crucial for the stability of CB4Se5.
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