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Updated: Jul 5, 2025
08:30
Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells
Published on: March 19, 2017
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Proton Irradiation on Halide Perovskites: Numerical Calculations
Alexandra V Rasmetyeva1, Stepan S Zyryanov1, Ivan E Novoselov1
1Institute of Physics and Technology, Ural Federal University, Mira 19 Street, 620002 Yekaterinburg, Russia.
Nanomaterials (Basel, Switzerland)
|January 11, 2024
Summary
Hybrid perovskites show potential for space solar cells, with MAPbI3, FAPbBr3, and FAPbI3 exhibiting low energy transfer. Mixed cation perovskites offer enhanced radiation resistance against proton flux.
Area of Science:
- Materials Science
- Solid State Physics
- Renewable Energy
Background:
- Hybrid perovskites are promising for solar cell applications.
- Understanding their response to radiation is crucial for space deployment.
Purpose of the Study:
- To evaluate the ionization, displacement, and heating effects of proton irradiation on hybrid perovskites.
- To identify perovskite compositions suitable for radiation-rich environments like space.
Main Methods:
- Numerical simulations using SRIM (Stopping and Range of Ions in Matter) and SCAPS (Solar Cell Capacitance Simulator) were employed.
- Calculations considered proton energies of 0.15, 3.0, and 18 MeV.
Main Results:
- MAPbI3, FAPbBr3, and FAPbI3 showed the lowest energy transfer, indicating high potential for space solar cells.
- Perovskites with mixed cations (FA, Cs) demonstrated superior stability against vacancy and phonon formation, showing promise as radiation-resistant materials.
- Proton energy deposition was found to be uniform across the solar cell depth and area at MeV energies.
Conclusions:
- Specific hybrid perovskite compositions are well-suited for space solar cell applications due to their radiation tolerance.
- Simple plastic film shielding is effective against low-energy protons, while mixed-cation formulations enhance resistance to higher fluxes.
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