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Updated: Jul 5, 2025

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Carbazole-based artificial light-harvesting system for photocatalytic cross-coupling dehydrogenation reaction
Guangping Sun1, Menghang Li1, Lijuan Cai1
1School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China. sunguangping1989@ntu.edu.cn.
Abstract:
A carbazole-based artificial light-harvesting system (LHS) was successfully fabricated based on the supramolecular assembly of AIE-enhanced donor (CTD), water-soluble phosphate-pillar[5]arene (WPP5), and eosin Y (ESY) acceptor. The formed WPP5-CTD possessed remarkable AIE emission, featuring an ideal energy donor for light harvesting. After encapsulation of ESY, the energy of WPP5-CTD was efficiently transferred to ESY in WPP5-CTD-ESY, and the antenna effect was 38.5, which was much higher than that of recently reported LHSs. Notably, WPP5-CTD-ESY was successfully utilized as a photocatalyst to realize the cross-coupling dehydrogenation reaction of diphenylphosphine oxide and benzothiazole derivatives, suggesting great potential for aqueous photocatalytic applications of this LHS.
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