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Energy transfer enhanced photoluminescence of 2D/3D CsPbBr3 hybrid assemblies
Chenxu Wang1, Jinhai Si1, Lihe Yan1
1Key Laboratory for Physical Electronics and Devices of the Ministry of Education and Shaanxi Key Laboratory of Photonics Technology for Information, School of Electronic Science and Engineering, Xi'an Jiaotong University, No. 28, Xianning West Road, Xi'an 710049, China.
Abstract:
Energy transfer has been proven to be an effective method to optimize optoelectronic conversion efficiency by improving light absorption and mitigating nonradiative losses. We prepared 2D/3D CsPbBr3 hybrid assemblies at different reaction temperatures using the hot injection method and found that the photoluminescence quantum yields (PLQYs) of these hybrids were greatly enhanced from 53.4% to 72.57% compared with 3D nanocrystals (NCs). Femtosecond transient absorption measurements were used to study the PLQY enhancement mechanisms, and it was found that the hot carrier lifetime improved from 0.36 to 1.88 ps for 2D/3D CsPbBr3 hybrid assemblies owing to the energy transfer from 2D nanoplates to 3D NCs. The energy transfer benefits the excited carrier accumulation and prolonged hot carrier lifetime in 3D NCs in hybrid assemblies, as well as PLQY enhancement in materials.
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