Hollow carbon-based materials for electrocatalytic and thermocatalytic CO₂ conversion

Electrocatalytic and thermocatalytic CO₂ conversions provide promising routes to realize global carbon neutrality, and the development of corresponding advanced catalysts is important but challenging. Hollow-structured carbon (HSC) materials with striking features, including unique cavity structure, good permeability, large surface area, and readily functionalizable surface, are flexible platforms for designing high-performance catalysts. In this review, the topics range from the accurate design of HSC materials to specific electrocatalytic and thermocatalytic CO₂ conversion applications, aiming to address the drawbacks of conventional catalysts, such as sluggish reaction kinetics, inadequate selectivity, and poor stability. Firstly, the synthetic methods of HSC, including the hard template route, soft template approach, and self-template strategy are summarized, with an evaluation of their characteristics and applicability. Subsequently, the functionalization strategies (nonmetal doping, metal single-atom anchoring, and metal nanoparticle modification) for HSC are comprehensively discussed. Lastly, the recent achievements of intriguing HSC-based materials in electrocatalytic and thermocatalytic CO₂ conversion applications are presented, with a particular focus on revealing the relationship between catalyst structure and activity. We anticipate that the review can provide some ideas for designing highly active and durable catalytic systems for CO₂ valorization and beyond.