Synergistic photocatalytic effect of α-Fe₂O₃-ZnO binary nanocatalyst toward methylene blue: An experimental design...

Due to the potential ecosystem protection and management applications, searching for highly optimized semiconductor-based solar energy photocatalysts is still a significant challenge. Coupled α-Fe₂O₃-ZnO nanoparticles were prepared in situ and characterized by various identification techniques such as XRD, SEM-EDX, TEM, DRS, and FT-IR. Its pHpzc was about 8.1. The band gap energies of ZnO, α-Fe₂O_3, and the coupled α-Fe₂O₃-ZnO system were 3.22, 2.08, and 2.09 eV, respectively. The boosted photocatalytic activity of the coupled catalysts was designed via the RSM approach, and the optimal RSM conditions were pH 5, 25 min irradiation time, and 0.3 g/L of the α-Fe₂O₃-ZnO containing 75 % ZnO. The center point conditions' run included 0.5 g/L of the coupled catalyst containing 50 % ZnO, pH 7, and 22.5 min illumination time. The study on scavenger agents showed the highest role of hydroxyl radicals in MB photodegradation by the proposed catalyst.