Related Experiment Video
Updated: Jul 5, 2025

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Entropy production in the nonreciprocal Cahn-Hilliard model.
Thomas Suchanek1, Klaus Kroy1, Sarah A M Loos2
1Institut für Theoretische Physik, Universität Leipzig, Postfach 100 920, D-04009 Leipzig, Germany.
This study explores a nonreciprocal Cahn-Hilliard model, revealing a traveling-wave phase driven by nonreciprocal coupling. Entropy production fluctuations near transitions signal the emergence of this dynamic phase.
Area of Science:
- Statistical Physics
- Non-Hermitian Physics
- Active Matter
Background:
- The nonreciprocal Cahn-Hilliard model serves as a model for non-Hermitian stochastic field theories.
- This model is inherently out of equilibrium due to nonreciprocal coupling, classifying it as an active field theory.
Purpose of the Study:
- To investigate the phases and transitions in the nonreciprocal Cahn-Hilliard model.
- To quantify scale-resolved time-reversal symmetry breaking and entropy production.
- To analyze the dynamics of the emergent traveling-wave phase.
Main Methods:
- Analysis of the nonreciprocal Cahn-Hilliard model with thermal noise.
- Fourier decomposition of the entropy production rate.
- Perturbative calculations in the low-noise regime.
Main Results:
- Identification of homogeneous, static-demixed, and traveling-wave phases.
- The traveling-wave phase is accessible via oscillatory instability or a critical exceptional point.
- Entropy production surges near static-dynamic transitions, driven by long-wavelength fluctuations, heralding the traveling wave.
Conclusions:
- The model exhibits rich phase behavior beyond conventional equilibrium systems.
- Time-reversal symmetry breaking is scale-resolved and depends on nonreciprocal coupling strength.
- The traveling-wave dynamics can be described as the motion of an active quasiparticle.
Related Concept Videos
Entropy Change in Reversible Processes
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
Carrier Generation and Recombination
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...
The Bohr Model
Entropy
When an ideal gas expands isothermally, the disorder in the gas increases. From the molecular perspective, the gas molecules have more volume to move around in.
Consider an infinitesimal step in the expansion, which...
Free Energy Changes for Nonstandard States
where R is the gas constant (8.314 J/K·mol), T is the absolute temperature in kelvin, and Q is the reaction quotient. This equation may be used to predict the spontaneity of a process under any given set of conditions.
Reaction Quotient...
Entropy and the Second Law of Thermodynamics
The relation between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...

