Related Experiment Video
Updated: Jul 5, 2025

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Entropy production in the nonreciprocal Cahn-Hilliard model
Thomas Suchanek1, Klaus Kroy1, Sarah A M Loos2
1Institut für Theoretische Physik, Universität Leipzig, Postfach 100 920, D-04009 Leipzig, Germany.
Abstract:
We study the nonreciprocal Cahn-Hilliard model with thermal noise as a prototypical example of a generic class of non-Hermitian stochastic field theories, analyzed in two companion papers [Suchanek, Kroy, and Loos, Phys. Rev. Lett. 131, 258302 (2023)10.1103/PhysRevLett.131.258302; Phys. Rev. E 108, 064123 (2023)10.1103/PhysRevE.108.064123]. Due to the nonreciprocal coupling between two field components, the model is inherently out of equilibrium and can be regarded as an active field theory. Beyond the conventional homogeneous and static-demixed phases, it exhibits a traveling-wave phase, which can be entered via either an oscillatory instability or a critical exceptional point. By means of a Fourier decomposition of the entropy production rate, we quantify the associated scale-resolved time-reversal symmetry breaking, in all phases and across the transitions, in the low-noise regime. Our perturbative calculation reveals its dependence on the strength of the nonreciprocal coupling. Surging entropy production near the static-dynamic transitions can be attributed to entropy-generating fluctuations in the longest wavelength Fourier mode and heralds the emerging traveling wave. Its translational dynamics can be mapped on the dissipative ballistic motion of an active (quasi)particle.
Related Concept Videos
Entropy Change in Reversible Processes
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
Carrier Generation and Recombination
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...
The Bohr Model
Entropy
When an ideal gas expands isothermally, the disorder in the gas increases. From the molecular perspective, the gas molecules have more volume to move around in.
Consider an infinitesimal step in the expansion, which...
Free Energy Changes for Nonstandard States
where R is the gas constant (8.314 J/K·mol), T is the absolute temperature in kelvin, and Q is the reaction quotient. This equation may be used to predict the spontaneity of a process under any given set of conditions.
Reaction Quotient...
Entropy and the Second Law of Thermodynamics
The relation between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...

