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Ce-regulating defect and morphology engineering for efficiently enhancing the piezocatalytic performances of BiOBr
Lihui Zhan1, Jindou Hu1, Yali Cao1
1State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, College of Chemistry, Xinjiang University, Urumqi, Xinjiang, P. R. China. caoyali523@163.com.
Abstract:
Cerium-doped bismuth oxybromide (1%, 5% and 10% Ce-BiOBr) piezocatalysts were synthesized. The piezocatalytic activity was efficiently regulated by defect and morphology engineering. Among them, the 5% Ce-BiOBr exhibits the highest piezocatalytic hydrogen production property with an evolution rate of 1147.6 μmol g-1 h-1, nearly twice that of the original BiOBr. Additionally, the MO dye degradation efficiency of 5% Ce-BiOBr reaches 91.9% within 60 min, with a higher reaction kinetic constant (0.0376 min-1) that was 6.1 times larger than that of pure BiOBr. These outstanding performances of 5% Ce-BiOBr surpass those of most other piezocatalytic material systems.

