3D pore-scale characterization of colloid aggregation and retention by confocal microscopy: Effects of fluid...

Understanding the mechanisms of colloid transport and retention as well as the spatial distribution of colloids in porous media is an important topic for contamination transport and remediation in subsurface environments. Utilizing advanced three-dimensional visualization experiments, we effectively capture the intricate distribution characteristics of colloids in the 3D pore space and quantify the size of colloid clusters that aggregate at fluid-fluid interfaces and solid surfaces during two-phase flow. Our experimental results reveal the influence of pore-scale events, such as Haines jumps and pinch-off, on colloid retention. Our results also indicate that large drainage rates can facilitate colloid retention on solid surfaces, especially under the condition of high ionic strength. This can be attributed to the migration of colloids from the fluid-fluid interface to the solid surface, propelled by transients in the local fluid structure. The findings reveal a synergistic effect of the ionic strength and hydrodynamic conditions on colloid transport and retention during two-phase flow and provide important insights for predicting the fate and transport of contaminants in soil and groundwater environments involving multiple fluid phases.