Magnetic superhydrophobic melamine sponges for crude oil removal from water

This paper proposes the preparation of a new sorbent material based on melamine sponges (MS) with superhydrophobic, superoleophilic, and magnetic properties. This study involved impregnating the surface of commercially available MS with eco-friendly deep eutectic solvents (DES) and Fe₃O₄ nanoparticles. The DES selection was based on the screening of 105 eutectic mixtures using COSMO-RS modeling. Other parameters affecting the efficiency and selectivity of oil removal from water were optimized using the Box-Bhenken model. Menthol:Thymol (1:1)@Fe₃O₄-MS exhibited the highest sorption capacity for real crude oils (101.7-127.3 g/g). This new sponge demonstrated paramagnetic behavior (31.06 emu/g), superhydrophobicity (151°), superoleophobicity (0°), low density (15.6 mg/cm³), high porosity (99 %), and excellent mechanical stability. Furthermore, it allows multiple regeneration processes without losing its sorption capacity. Based on these benefits, Menthol:Thymol (1:1)@Fe₃O₄-MS shows promise as an efficient, cost-effective, and eco-friendly substitute for the existing sorbents.