Artificial Processive Catalytic Systems
Roeland J M Nolte1, Johannes A A W Elemans1
1Radboud University, Institute for Molecules and Materials, Heyendaalseweg 125, 6525AJ, Nijmegen, The, Netherlands.
Abstract:
Processive catalysts remain attached to a substrate and perform multiple rounds of catalysis. They are abundant in nature. This review highlights artificial processive catalytic systems, which can be divided into (A) catalytic rings that move along a polymer chain, (B) catalytic pores that hold polymer chains and decompose them, (C) catalysts that remain attached to and move around a cyclic substrate via supramolecular interactions, and (D) anchored catalysts that remain in contact with a substrate via multiple catalytic interactions (see frontispiece).
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