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Catalysis02:50

Catalysis

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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For many years, scientists thought that enzyme-substrate binding took place in a simple "lock-and-key" fashion. This model stated that the enzyme and substrate fit together perfectly in one instantaneous step. However, current research supports a more refined view scientists call induced fit. The induced-fit model expands upon the lock-and-key model by describing a more dynamic interaction between enzyme and substrate. As the enzyme and substrate come together, their interaction causes...
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Catalytically Perfect Enzymes01:07

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The theory of catalytically perfect enzymes was first proposed by W.J. Albery and J. R. Knowles in 1976. These enzymes catalyze biochemical reactions at high-speed. Their catalytic efficiency values range from 108-109 M-1s-1. These enzymes are also called 'diffusion-controlled' as the only rate-limiting step in the catalysis is that of the substrate diffusion into the active site. Examples include triose phosphate isomerase, fumarase, and superoxide dismutase.
 
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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

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Introduction
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Olefin Metathesis Polymerization: Overview01:13

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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Related Experiment Video

Updated: Jul 4, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
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Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

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Artificial Processive Catalytic Systems.

Roeland J M Nolte1, Johannes A A W Elemans1

  • 1Radboud University, Institute for Molecules and Materials, Heyendaalseweg 125, 6525AJ, Nijmegen, The, Netherlands.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|February 5, 2024
PubMed
Summary
This summary is machine-generated.

This review explores artificial processive catalysts, which stay attached to substrates for multiple catalytic cycles. We highlight four main types: catalytic rings, pores, supramolecularly attached catalysts, and anchored catalysts.

Keywords:
Supramolecular catalysiscatalytic macrocycleshost-guestprocessive catalytic depolymerizationrotaxanes

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Area of Science:

  • Catalysis
  • Supramolecular Chemistry
  • Polymer Science

Background:

  • Processive catalysts, which remain bound to a substrate during multiple catalytic cycles, are abundant in nature.
  • Understanding these natural systems provides a basis for designing artificial counterparts.

Purpose of the Study:

  • To review and categorize artificial processive catalytic systems.
  • To highlight advancements in the design and application of artificial processive catalysts.

Main Methods:

  • Categorization of artificial processive catalysts based on their mechanism of action and substrate interaction.
  • Review of existing literature on catalytic rings, pores, supramolecularly attached catalysts, and anchored catalysts.

Main Results:

  • Identified four main classes of artificial processive catalytic systems: (A) catalytic rings moving along polymers, (B) catalytic pores decomposing polymers, (C) catalysts interacting with cyclic substrates via supramolecular bonds, and (D) anchored catalysts maintaining substrate contact through multiple interactions.
  • Demonstrated the diversity and potential of artificial processive catalysts.

Conclusions:

  • Artificial processive catalysts offer versatile platforms for various chemical transformations.
  • Further research in this area can lead to novel catalytic applications and biomimetic systems.