Regulating the spatial arrangement of CuO and MgO within activated carbon matrix to maximize their room temperature...

Adsorbents with dual-component active phases have attracted much attention owing to their potential application in synergistic H₂S removal. The influence of spatial arrangements of two components within a support matrix on their desulfurization performance was investigated through regulating the mutual arrangements of CuO and MgO on an activated carbon surface. Their spatial locations were found to remarkably affect interfacial interactions, local pH, the conductivity of adsorbents, and electronic structure of copper oxide. A close contact of CuO with the carbon surface led to strong interactions of both components, inhibiting the reduction of CuO and decreasing its reactivity with H₂S. On the other hand, a proximity of MgO to the carbon surface increased local pH, promoting the oxidation of H₂S into elemental S, instead of sulfates. Cu⁺ in the copper oxide phase increased the desulfurization performance due to its ability to activate oxygen and to accelerate a lattice diffusion. Enhanced surface conductivity due to the interfacial interactions improved the desulfurization efficiency and favored the formation of elemental S through promoting an electron transfer in redox reactions.