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Enhancing disinfection and microcontaminant removal by coupling LED driven UVC and UVA/photo-Fenton processes in
Alam G Trovó1, María Guadalupe Pinna-Hernández2, Paula Soriano-Molina2
1Solar Energy Research Centre (CIESOL), Joint Centre University of Almeria-CIEMAT, Ctra. de Sacramento s/n, Almería 04120, Spain; Universidade Federal de Uberlândia, Instituto de Química, 38400-902 Uberlândia, MG, Brazil.
This study demonstrates that sequential UV-C Light Emitting Diode (LED) and photo-Fenton processes can reclaim wastewater for agricultural irrigation. The combined system effectively removes microcontaminants and meets European water quality standards.
Area of Science:
- Environmental Engineering
- Water Treatment Technologies
- Photocatalysis
Background:
- Wastewater reclamation is crucial for sustainable water management, especially for agricultural irrigation.
- The new European Regulation (EU 2020/741) sets strict standards for reclaimed water quality.
- Assessing advanced oxidation processes (AOPs) in continuous flow is vital for practical application.
Purpose of the Study:
- To evaluate the sequential combination of UV-C LED and photo-Fenton/UVA-LED processes for wastewater reclamation.
- To determine the efficacy of these processes in achieving water quality class B for agricultural reuse.
- To assess the impact of bacterial load on microcontaminant removal.
Main Methods:
- Continuous flow system utilizing sequential UV-C LED (276 nm) and photo-Fenton/UVA-LED (376 nm) irradiation.
- Variable hydraulic residence times (HRTs) and liquid depths were tested.
- Analysis of Escherichia coli inactivation and removal of organic microcontaminants.
Main Results:
- UV-C LED alone achieved water quality class B for low bacterial loads at 6.5 min HRT.
- Higher bacterial loads required HRTs exceeding 30 min for UV-C LED treatment.
- The sequential UVC and UVA/photo-Fenton systems removed 58 ± 4% of organic microcontaminants, meeting class B standards.
Conclusions:
- Sequential UV-C LED and photo-Fenton/UVA-LED processes are effective for wastewater reclamation for agricultural irrigation.
- The system can achieve the required water quality standards under continuous flow conditions.
- The combined AOP approach offers a promising solution for microcontaminant removal in wastewater reuse.
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