An Integrated Approach for Piezo-Electrochemical Nanoenergy Generation, Storage, and Real-Time Electromagnetic
Prem Pal Singh1, Bhanu Bhusan Khatua1
1Materials Science Centre, Indian Institute of Technology Kharagpur, Kharagpur 721302, India.
Abstract:
The extensive utilization of high-end wireless electronic equipment in medical, robotics, satellite, and military communications has created a pressing challenge for real-time electromagnetic interference (EMI) control. Herein, a piezo-powered self-chargeable supercapacitor (PPSC) architecture based on an iron-doped graphitic nitride (Fe-g-C3N4: FGN) electrode with a solid piezoelectrolyte is devised, which can provide real-time controlled EMI shielding through piezo-powered self-charging voltage (SCV). This PPSC device along with real-time SCV-controlled EMI shielding also integrates additional features like nanoenergy generation and storing capability. The results demonstrate that the PPSC device is capable of exhibiting a piezo-tuned self-charging ability of up to 669.2 mV under 9.47 N of dynamic pressing for 180 s. The SCV electrostatically modifies the PPSC device that causes destructive interference and governs the absorption of electromagnetic radiation (EMR) and controls the absorption-dominated EMI shielding up to 59.2 dB at 500 mV. Additionally, the SCV-led electrification of the PPSC device also controls a unique functional transition from the EMR reflector to the EMR absorber at ∼90 mV. Hence, this strategy of tailored absorption and reflection adjustments of EMR could also potentially contribute toward the advancement of stealth technology for military armaments with externally controlled stealth capabilities.
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