Superhydrophobic sand evaporator with core-shell structure for long-term salt-resistant solar desalination

Solar-driven water evaporation, as an environmentally benign pathway, provides an opportunity for alleviating global clean water scarcity. However, the rapidly generated interfacial steam and localized heating could cause increased salt concentration and accumulation, deteriorating the evaporation performance and long-term stability. Herein, a novel superhydrophobic sand solar (FPPSD) evaporator with a core-shell structure was proposed through interface functionalization for continuous photothermal desalination. The collective behavior essence of the sand aggregate gave itself micron-scale self-organized pores and configurable shapes, generating desirable capillary force and supplying effective water-pumping channels. More importantly, combining the dopamine, polypyrrole (PPy), and 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDTS) through π-π conjugation and multiple hydrogen bonding effects gave the FPPSD evaporator with stable superhydrophobic property and highly efficient photothermal conversion capability. Therefore, the FPPSD evaporator showed a continuous and stable photothermal performance even after 96 h continuous evaporation under 3-sun irradiation for 10 wt% saline solution, among the best values in the reported works of literature, demonstrating its excellent salt-resistance stability. Furthermore, this novel FPPSD evaporator displayed outstanding environmental stability that kept its initial water transport capacity even after being treated under harsh conditions for 30 days. With excellent salt-resistance ability and stable environmental stability, the FPPSD evaporator will provide an attractive platform for sustainable solar-driven water management.