Kinetic trapping of nanoparticles by solvent-induced interactions

Theoretical analysis based on mean field theory indicates that solvent-induced interactions (i.e. structural forces due to the rearrangement of wetting solvent molecules) not considered in DLVO theory can induce the kinetic trapping of nanoparticles at finite nanoscale separations from a well-wetted surface, under a range of ubiquitous physicochemical conditions for inorganic nanoparticles of common materials (e.g., metal oxides) in water or simple molecular solvents. This work proposes a simple analytical model that is applicable to arbitrary materials and simple solvents to determine the conditions for direct particle-surface contact or kinetic trapping at finite separations, by using experimentally measurable properties (e.g., Hamaker constants, interfacial free energies, and nanoparticle size) as input parameters. Analytical predictions of the proposed model are verified by molecular dynamics simulations and numerical solution of the Smoluchowski diffusion equation.