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Related Concept Videos

Gas Chromatography: Types of Detectors-II01:19

Gas Chromatography: Types of Detectors-II

In gas chromatography, different detectors are employed to meet specific analytical needs. These detectors are often categorized based on their detection mechanisms and the types of compounds they are best suited to analyze. Thermal Conductivity Detectors (TCD), Flame Ionization Detectors (FID), and Electron Capture Detectors (ECD) represent common categories, each with unique operating principles and applications. However, beyond these, several other detectors are designed for more specialized...
High-Performance Liquid Chromatography: Types of Detectors01:15

High-Performance Liquid Chromatography: Types of Detectors

The role of the detectors in High-Performance Liquid Chromatography (HPLC) is to analyze the solutes as they exit from the chromatographic column. The detector recognizes the solute's property and generates corresponding electrical signals, which are converted into a readable graph of the detector's response versus elution time called a chromatogram at the computer. There are several types of HPLC detectors, each with its own advantages and limitations, depending on the analyte properties and...
Atomic Emission Spectroscopy: Overview01:20

Atomic Emission Spectroscopy: Overview

Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...
Atomic Emission Spectroscopy: Instrumentation01:22

Atomic Emission Spectroscopy: Instrumentation

The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers.  Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
Atomic Emission Spectroscopy: Lab01:29

Atomic Emission Spectroscopy: Lab

AES is a powerful analytical technique, especially effective when used with plasma sources, producing abundant spectra in characteristic emission lines. The Inductively Coupled Plasma (ICP), in particular, yields superior quantitative analytical data due to its high stability, low noise, low background, and minimal interferences under optimal experimental conditions. However, newer air-operated microwave sources are emerging as promising alternatives that could be more cost-effective than...

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Synthesis and Characterization of High c-axis ZnO Thin Film by Plasma Enhanced Chemical Vapor Deposition System and its UV Photodetector Application
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Ionic Conduction-Based Polycrystalline Oxide Gamma Ray Detection - Radiation-Ionic Effects.

Thomas Defferriere1, Ahmed Sami Helal2,3, Ju Li1,2

  • 1Department of Material Science and Engineering, MIT, Cambridge, MA, 02139, USA.

Advanced Materials (Deerfield Beach, Fla.)
|February 21, 2024
PubMed
Summary
This summary is machine-generated.

Newly discovered radiation-ionic effects in ceramics enable sensitive gamma-ray detection. This breakthrough in metal oxide functional ceramics offers opportunities for low-power, miniaturizable solid-state radiation detectors.

Keywords:
electroceramicspolycrystallineradiation detectionradiation‐ionicsolid electrolytes

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Area of Science:

  • Materials Science
  • Solid-state Physics
  • Ceramic Engineering

Background:

  • Opto-ionic effects in metal oxides offer novel functional ceramic applications.
  • Previously, opto-ionic effects were observed in thin films under ultraviolet (UV) irradiation.
  • Generalizing this to bulk materials for radiation detection is a new frontier.

Purpose of the Study:

  • To investigate and generalize the opto-ionic effect to a radiation-ionic effect for gamma-ray detection in bulk ceramic materials.
  • To demonstrate the potential of lightly doped Gadolinium-doped Cerium Oxide (Gd-doped CeO2) for radiation detection applications.

Main Methods:

  • Utilized lightly doped Gd-doped CeO2, a polycrystalline ion-conducting ceramic.
  • Exposed the ceramic to 60Co gamma-ray (1.1 and 1.3 MeV) radiation near room temperature.
  • Measured the resistance ratio change and ionic current response under low electrical fields (< 2 V cm-1).

Main Results:

  • Observed a significant resistance ratio change of approximately 10^3.
  • Demonstrated a reversible response in ionic current upon exposure to gamma-ray radiation.
  • Attributed the effect to the passivation of space charge barriers at grain boundaries, modulating ionic carrier flow.

Conclusions:

  • The radiation-ionic effect in bulk ceramics enables sensitive gamma-ray detection.
  • This phenomenon allows for the development of inexpensive, sensitive, low-power, and miniaturizable solid-state devices.
  • Potential applications include radiation detectors for geothermal drilling, small modular reactors, nuclear security, and waste management, especially in harsh environments.