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A One-Step Approach for a Durable and Highly Hydrophobic Coating for Flax Fabrics for Self-Cleaning Application
Antoine Ishak1, Rodolphe Sonnier1, Belkacem Otazaghine1
1PCH, IMT-Mines Alès, 6, Avenue de Clavières, 30100 Alès, France.
Molecules (Basel, Switzerland)
|February 24, 2024
Summary
Researchers developed durable, highly hydrophobic flax fabrics using dip-coating with polysiloxane for self-cleaning applications. The treated fabrics show excellent durability and water repellency, with controllable mechanical property changes.
Area of Science:
- Materials Science
- Textile Engineering
- Surface Chemistry
Background:
- Developing advanced textile functionalities is crucial for applications like self-cleaning surfaces.
- Hydrophobic treatments enhance fabric performance but often lack durability.
- Flax fabrics offer a sustainable base material for functionalization.
Purpose of the Study:
- To create highly hydrophobic and durable flax fabrics for self-cleaning applications.
- To investigate the effect of polysiloxane coating on fabric properties.
- To explore methods for controlling mechanical property changes during coating.
Main Methods:
- Utilized a dip-coating method to apply a polysiloxane coating to flax fabrics.
- Employed a hydrosilylation reaction with a Karstedt catalyst at room temperature.
- Analyzed hydrophobic properties using contact and sliding angle measurements.
- Evaluated fabric durability and self-cleaning performance.
- Assessed changes in mechanical properties (E modulus, tensile stress, elongation).
Main Results:
- Achieved highly hydrophobic flax fabrics with a contact angle of ~145° and sliding angle of ~23°.
- Demonstrated good self-cleaning ability for specific pollutants and excellent coating durability.
- Observed a decrease in the elastic modulus and an increase in tensile stress and elongation at maximum force.
- Showed that mechanical property modifications can be controlled by adjusting the curing agent proportion.
Conclusions:
- The dip-coating of flax fabrics with polysiloxane via hydrosilylation yields durable, hydrophobic materials suitable for self-cleaning.
- The coating process offers tunable control over the mechanical properties of the treated fabrics.
- This method presents a viable approach for enhancing flax fabric performance for advanced applications.
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