Synthesis and structural characterization of stable coinage metal (Cu, Ag, Au) cyclopentadienyl complexes
Robin Sievers1, Marc Reimann2, Nico G Kub1
1Freie Universität Berlin Fabeckstraße 34/36 14195 Berlin Germany moritz.malischewski@fu-berlin.de.
Abstract:
The electron withdrawing and oxidatively stable perfluorinated Cp* ligand [C5(CF3)5]- allowed for the isolation of rare and unusually stable coinage metal complexes [M(C5(CF3)5)(PBu3)] (M = Cu, Ag, Au), representing the first complete and structurally comparable series of group 11 Cp coordination compounds. Full characterization and structure analysis revealed distinct and partly unknown coordination motifs with hapticities ranging from η1, η3/η1 and η3/η2 for gold, silver and copper, respectively. Quantum-chemical studies using DFT methods confirm these findings and connect them to the unique electronic structure of the given ligand system.
Related Concept Videos
Complexation Equilibria: Factors Influencing Stability of Complexes
Stability of Substituted Cyclohexanes
The two chair conformations of cyclohexanes undergo rapid interconversion at room temperature. Both forms have identical energies and stabilities, each comprising equal amounts of the equilibrium mixture. Replacing a hydrogen atom with a functional group makes the two conformations energetically non-equivalent.
For example, in...
Aromatic Hydrocarbon Cations: Structural Overview
Removing one hydrogen from the intervening CH2 group...
Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
Properties of Organometallic Compounds
Valence Bond Theory


