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Updated: Jul 2, 2025

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Ice-Templated Synthesis of Atomic Cluster Cocatalyst with Regulable Coordination Number for Enhanced Photocatalytic
Haifeng Wang1, Fan Wang2, Shengjia Zhang3
1State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, P. R. China.
Abstract:
Supported metal catalysts have been exploited in various applications. Among them, cocatalyst supported on photocatalyst is essential for activation of photocatalysis. However, cocatalyst decoration in a controllable fashion to promote intrinsic activity remains challenging. Herein, a versatile method is developed for cocatalyst synthesis using an ice-templating (ICT) strategy, resulting in size control from single-atom (SA), and atomic clusters (AC) to nanoparticles (NP). Importantly, the coordination numbers (CN) of decorated AC cocatalysts are highly controllable, and this ICT method applies to various metals and photocatalytic substrates. Taking narrow-band gap Ga-doped La5Ti2Cu0.9Ag0.1O7S5 (LTCA) photocatalyst as an example, supported Ru AC/LTCA catalysts with regulable Ru CNs have been prepared, delivering significantly enhanced activities compared to Ru SA and Ru NPs supported on LTCA. Specifically, Ru(CN = 3.4) AC/LTCA with an average CN of Ru─Ru bond measured to be ≈3.4 exhibits excellent photocatalytic H2 evolution rate (578 µmol h-1) under visible light irradiation. Density functional theory calculation reveals that the modeled Ru(CN = 3) atomic cluster cocatalyst possesses favorable electronic properties and available active sites for the H2 evolution reaction.
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