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Nanofibrous Biomaterial-Based Passive Cooling Paint Structurally Linked by Alkane-Oleate Interactions
Andrew Caratenuto1, Kyle Leach1, Yang Liu1
1Department of Mechanical and Industrial Engineering, Northeastern University, Boston, Massachusetts 02115, United States.
ACS Applied Materials & Interfaces
|March 1, 2024
Summary
This study introduces a novel paint-like passive cooling material using hydroxyapatite fibers. This innovative solution offers efficient cooling without electricity, reducing greenhouse gas emissions and enhancing thermal comfort.
Area of Science:
- Materials Science
- Nanotechnology
- Sustainable Energy
Background:
- Passive radiative cooling materials offer electricity-free cooling, crucial for reducing greenhouse gas emissions and improving thermal comfort in underserved regions.
- Optimizing material properties, ease of application, and scalability are critical for real-world deployment of passive cooling technologies.
Purpose of the Study:
- To develop an easy-to-apply, paint-like passive cooling solution using embedded hydroxyapatite nanoscale fibers.
- To investigate the chemical structure, bonding behaviors, and cooling performance of the developed composite material.
Main Methods:
- Embedding hydroxyapatite nanoscale fibers in an oil-based medium to create a paint-like solution.
- Utilizing Fourier-transform infrared spectroscopy (FTIR) to analyze chemical structure and bonding.
- Evaluating outdoor cooling performance under solar irradiance.
Main Results:
- The composite material reflects 95% of solar energy and emits 92% of its radiative output through the atmospheric transparency window.
- Achieved an average subambient cooling performance of 3.7 °C under outdoor conditions (800 W m-2 solar irradiance).
- Demonstrated tunable surface properties, enhanced durability, and potential for recycling.
Conclusions:
- The developed hydroxyapatite-based paint offers an effective and scalable passive cooling solution.
- Its properties make it suitable for outdoor applications, promoting sustainable cooling and circular economy principles.
- The material's ease of application and tunable characteristics position it as a promising candidate for passive cooling coatings.

