A Review on Use of Emulsified Acids for Matrix Acidizing in Carbonate Reservoirs

Almost 60% of oil and 40% of gas reserves worldwide are contained in carbonate reservoirs where acidizing stimulation is more challenging compared to sandstone reservoirs. Utilization of emulsified acids in matrix acidizing operations has been the most effective technique for more than half a century. This is due to the colloidal system's ability to generate deep, narrow conduits toward production zones under controlled retarded reactivity with the rock surface, along with the excellent sweep efficiency and corrosion inhibition of the well equipment. This Review attempts to review the various kinds of emulsified acids that are used for matrix acidizing of carbonate formations. The Review is trying to trace the innovations that have, gradually, been applied for enhancing the performance of emulsified acids for a variety of conditions, their limitations, and the developmental solutions such hybrid emulsifiers and pickering emulsions. In addition, the Review also discusses the parameters, characteristics, and measuring techniques required for the successful synthesis of a stable and quality emulsion while considering the environmental concerns raised toward the application of an emulsified acid system. From the reviewed publications, it can be summarized that macroemulsions are best suited for matrix acidizing applications over microemulsions due to low emulsifier concentrations and high acid volume retention; similarly, water in oil emulsions provide better retardation in a comparison to oil in water emulsions. The small droplet size of the emulsion yields high viscosity and stability. The compositional balance between each component present in the acidizing system is a crucial factor for optimum performance. Moreover, for future practice, much focus is required to design emulsified acids as ecofriendly systems that can leave the least amount of toxicity during and after implementation.