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Updated: Jun 30, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Virial equation of state for a granular system
Subhanker Howlader1, Prasenjit Das2
1Department of Physical Sciences, Indian Institute of Science Education and Research Mohali, Knowledge City, Sector 81, SAS Nagar, Mohali, Punjab, 140306, India.
Abstract:
The equation of state for an ideal gas is simple, which is . In the case of imperfect gases where mutual interactions among the constituents are important, pressure P can be expressed as the series expansion of density n with appropriate coefficients, known as virial coefficients . In this paper, we have obtained the first four virial coefficients for a model interaction potential using multidimensional Monte-Carlo integration and importance sampling methods. Next, we perform molecular dynamics simulations with the same for a many-particle system to obtain P as a function of T and n. We compare our numerical data with the virial equation of state.
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