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Updated: Jun 30, 2025

Angle-resolved Photoemission Spectroscopy At Ultra-low Temperatures
Published on: October 9, 2012
Analyzing the photoassociation spectrum of ultracold 85Rb 133Cs molecule in (3)3Σ+ state
Zi-Wei Wang1, Zi-Ang Li1, Xu-Hui Bai1
1School of Physics, Dalian University of Technology, Dalian 116024, China.
Abstract:
We establish a theoretical model to analyze the photoassociative spectroscopy of 85Rb 133Cs molecules in the (3)3Σ+ state. The vibrational energy, spin-spin coupling constant, and hyperfine interaction constant of the (3)3Σ+ state are determined based on nine observed vibrational levels. Consequently, the Rydberg-Klein-Rees potential energy curve of the (3)3Σ+ state is obtained and compared with the ab initial potential energy curve. Our model can be adopted to analyze the photoassociative spectroscopy of other heteronuclear alkali-metal diatomic molecules in the (3)3Σ+ state.
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