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Updated: May 9, 2026

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
Published on: April 27, 2018
Constructing Chainmail-Structured CoP/C Nanospheres as Highly Active Anodic Electrocatalysts for Oxygen Evolution
Yang Nan1, Tianpeng Liu1, Wenhao Liu1
1State Key Laboratory of Organic-Inorganic Composites and College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China.
Abstract:
Constructing highly active and noble metal-free electrocatalysts is significant for the anodic oxygen evolution reaction (OER). Herein, uniform carbon-coated CoP nanospheres (CoP/C) are developed by a direct impregnation coupling phosphorization approach. Importantly, CoP/C only takes a small overpotential of 230 mV at the current density of 10 mA cm-2 and displays a Tafel slope of 56.87 mV dec-1. Furthermore, the intrinsic activity of CoP/C is 21.44 times better than that of commercial RuO2 under an overpotential of 260 mV. In situ Raman spectroscopy studies revealed that a large number of generated Co-O and Co-OH species could facilitate the *OH adsorption, effectively accelerating the reaction kinetics. Meanwhile, the carbon shell with a large number of mesoporous pores acts as the chainmail of CoP, which could improve the active surface area of the catalyst and prevent the Co sites from oxidative dissolution. This work provides a facile and effective reference for the development of highly active and stable OER catalysts.
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