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3D printing of reactive macroporous polymers via thiol-ene chemistry and polymerization-induced phase separation

Nikolaj K Mandsberg1, Fatma Aslan1, Zheqin Dong1,2

  • 1Karlsruhe Institute of Technology (KIT), Institute of Biological and Chemical Systems - Functional Molecular Systems (IBCS-FMS), Kaiserstrasse 12, Karlsruhe 76131, Germany. zheqindong@sdu.edu.cn.

Chemical Communications (Cambridge, England)
|March 22, 2024
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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
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