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Updated: Jun 29, 2025

Generation of Zerovalent Metal Core Nanoparticles Using n-2-aminoethyl-3-aminosilanetriol
Published on: February 11, 2016
{N-[1-(2-Oxidophen-yl)ethyl-idene]-dl-alaninato}(pentane-1,5-di-yl)silicon(IV)
1Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, Germany.
Abstract:
The title SiIV complex, C16H21NO3Si, is built up by a tridentate dinegative Schiff base ligand bound to a sila-cyclo-hexane unit. The coordination geometry of the penta-coordinated SiIV atom is a distorted trigonal bipyramid. The presence of the sila-cyclo-hexane ring in the complex leads to an unusual coordination geometry of the SiIV atom with the N atom from the Schiff base ligand and an alkyl-C atom in apical positions of the trigonal bipyramid. There is a disorder of the methyl group at the imine bond with two orientations resolved for the H atoms [major orientation = 0.55 (3)]. In the crystal, C-H⋯O inter-actions are found within corrugated layers of mol-ecules parallel to the ab plane.
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