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Published on: January 29, 2013
Development of High-Performance Polyindole/Silicon Carbide Nanocomposites for Optoelectrical and Sensing Applications
R Gopika1, K Arun1, M T Ramesan1
1Centre for Polymer Science and Technology, Department of Chemistry, University of Calicut, Calicut University P.O., Malappuram, Kerala 673 635, India.
Abstract:
In this study, silicon carbide (SiC)-reinforced polyindole (PIn) nanocomposites were prepared by a simple in situ polymerization method. The successful reinforcement of the nanofiller within the host matrix was characterized using different analytical techniques. The chemical bonding of SiC in the polymer was identified by the characteristic peak around 800 cm1 using Fourier transform infrared spectroscopy (FT-IR). The increment in intensity of the absorption and enhanced crystallinity of the samples upon the addition of nanofillers were analyzed using UV-vis spectroscopy and X-ray diffraction (XRD). The prepared specimens showed reduced optical bandgap energy (3.188 eV) and Urbach energy (2.315 meV) with an improved refractive index (2.348). The effect of nanoparticles on the surface morphology of the nanocomposites was studied using scanning electron microscopy (SEM), and a uniform dispersion of fillers in the matrix was found for PInSiC7. A high-resolution transmission electron microscopy (HR-TEM) revealed the shape and average particle size of the sample. X-ray electron spectroscopy (XPS) measurements confirmed the formation of the nanocomposite by exhibiting the presence of all elements in the corresponding spectra. The thermal stability and glass transition temperature of the nanocomposites were significantly improved with the addition of SiC. The temperature-dependent AC conductivity, dielectric parameters, complex impedance, and electrical modulus were also evaluated using an impedance analyzer. The increased electrical characteristics of the PInSiC7 sample can be attributed to the uniform spread and strong synergetic interaction of SiC with PIn. The results thus showcased the potential of the samples for use in optical and energy storage applications. This study was also extended to understand the ammonia sensing properties, which make it possible to design and develop gas sensors using the PInSiC nanocomposites.
