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Pressure Indicator Composite Films via Compressive Deformation of a Translucent Matrix Containing a Contrasting
Ali Ammar1, Justin D Smith1, Ugur Aslan1
1William A. Brookshire Department of Chemical and Biomolecular Engineering, Cullen College of Engineering, University of Houston, Houston, Texas 77204, United States.
ACS Applied Materials & Interfaces
|April 8, 2024
Summary
New cellulose acetate composites with activated charcoal change color under pressure. This pressure-responsive material shows a linear brightness change with applied force, useful for impact assessment.
Area of Science:
- Materials Science
- Polymer Science
- Nanotechnology
Background:
- Pressure-induced color change is a poorly understood phenomenon.
- Cellulose acetate is a versatile polymer for composite development.
Purpose of the Study:
- To demonstrate a novel pressure-responsive color change mechanism in cellulose acetate composites.
- To investigate the effect of activated charcoal filler on pressure sensitivity.
- To explore the utility of these composites as optical impact indicators.
Main Methods:
- Preparation of cellulose acetate composites with varying activated charcoal loadings (1-7 wt%) via direct immersion annealing (DIA).
- Compression testing to evaluate pressure-induced changes in material brightness.
- Cross-sectional scanning electron microscopy (SEM) to analyze material morphology.
- Ball drop tests to assess indicator performance in impact scenarios.
Main Results:
- A linear relationship was observed between applied pressure (12-56 MPa) and the brightness of pressure marks in composites with 1-7 wt% activated charcoal.
- The porous morphology resulting from DIA was crucial for tuning the sensitivity of the pressure indicators.
- The developed composites demonstrated robustness and utility in optical impact assessment via simple ball drop tests.
Conclusions:
- Direct immersion annealing (DIA) enables a neglected mechanism for pressure-responsive color change in cellulose acetate composites.
- The sensitivity of these pressure indicators can be effectively tuned by controlling activated charcoal content and material morphology.
- These composites offer a promising, robust solution for optical impact assessment.

