Knot Architecture for Biocompatible and Semiconducting 2D Electronic Fiber Transistors

Wearable devices have generally been rigid due to their reliance on silicon-based technologies, while future wearables will utilize flexible components for example transistors within microprocessors to manage data. Two-dimensional (2D) semiconducting flakes have yet to be investigated in fiber transistors but can offer a route toward high-mobility, biocompatible, and flexible fiber-based devices. Here, the electrochemical exfoliation of semiconducting 2D flakes of tungsten diselenide (WSe₂) and molybdenum disulfide (MoS₂) is shown to achieve homogeneous coatings onto the surface of polyester fibers. The high aspect ratio (>100) of the flake yields aligned and conformal flake-to-flake junctions on polyester fibers enabling transistors with mobilities μ ≈1 cm² V^-1 s^-1 and a current on/off ratio, I_on/I_off ≈10²-10⁴. Furthermore, the cytotoxic effects of the MoS₂ and WSe₂ flakes with human keratinocyte cells are investigated and found to be biocompatible. As an additional step, a unique transistor 'knot' architecture is created by leveraging the fiber diameter to establish the length of the transistor channel, facilitating a route to scale down transistor channel dimensions (≈100 µm) and utilize it to make a MoS₂ fiber transistor with a human hair that achieves mobilities as high as μ ≈15 cm² V^-1 s^-1.