Dual-Phase Structure through Selective Etching of the Double A-Element MAX Phase in Lewis Acidic Molten Salts

Two-dimensional (2D) MXene materials with innovative properties and versatile applications have gained immense popularity among scientists. The green and environmentally friendly Lewis acid salt etching route has opened up immense possibilities for the advancement of 2D MXene materials. In this study, we precisely etched the Al element from the double A-element MAX phases Ti₂(SnAl_1-)C by employing Lewis molten salt guided by redox potentials. This approach led to the discovery of a novel Ti₂SnCCl dual-phase structure consisting of Ti₂SnC and Ti₂CCl. We then established that the etching of the MAX phase via Lewis acid salt is facilitated by the oxidation of M-site elements, with the MX sublayer acting as an electron transmission conduit to enable the oxidation of A-site elements. This work is dedicated to unraveling the underlying mechanisms governing the etching processes using Lewis molten salt, thereby contributing to a more profound comprehension of these innovative etching routes.