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Updated: Jun 27, 2025

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
Published on: November 22, 2016
Combining geometric constraint and redox non-innocence within an ambiphilic PBiP pincer ligand
Peter Coburger1, Ana Guilherme Buzanich2, Franziska Emmerling2,3
1Department of Inorganic Chemistry, Technische Universität München Lichtenbergstr. 4 85747 Garching Germany.
Abstract:
The synthesis of the first pincer ligand featuring a strictly T-shaped group 15 element and its coordination behaviour towards transition metals is described. The platform is itself derived from a trianionic redox non-innocent NNN scaffold. In addition to providing a rigid coordination environment to constrain a Bi centre in a T-shaped geometry to manipulate its frontier molecular orbital constitution, the NNN chelate displays highly covalent bonding towards the geometrically constrained Bi centre. The formation of intriguing ambiphilic Bi-M bonding interactions is demonstrated upon formation of a pincer complex as well as a multimetallic cluster. All compounds are comprehensively characterised by spectroscopic methods including X-ray Absorption Near Edge Structure (XANES) spectroscopy and complemented by DFT calculations.
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