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Intercalating a potassium-aqua complex cation into an α-MoO3 layer without reducing molybdenum: a potential storage
Debu Jana1, Shalini Sanjay Mishra1, Samar K Das1
1School of Chemistry, University of Hyderabad, P.O. Central University, Hyderabad - 500046, India. skdas@uohyd.ac.in.
Abstract:
We have demonstrated a green aqueous synthesis of rod-shaped MoO3 material, [MoVI3O9{K(H2O)4}(CH3COO)]·H2O (2) intercalating potassium-aqua-complex acetate into its lamellar space, simply by ion-exchange of Co(II)-aqua-complex in compound [MoVI4O12(CH3COO)2{CoII(H2O)6}]·2H2O (1) by {K(H2O)4}+ in an aqueous solution of 1 and KCl. Compound 2 acts as a potential storage system of alkali metal ions.
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