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Updated: Jun 27, 2025

A Micropatterning Assay for Measuring Cell Chirality
Published on: March 11, 2022
Axially-chiral boramidine for detailed (chir)optical studies
Nidal Saleh1, Estefanía Sucre-Rosales2, Francesco Zinna3
1Department of Organic Chemistry, University of Geneva Quai Ernest Ansermet 30 1211 Geneva 4 Switzerland nidal.saleh@unige.ch jerome.lacour@unige.ch.
Abstract:
The inclusion of boron atoms into chiral π-conjugated systems is an effective strategy to unlock unique chiroptical properties. Herein, the preparation and characterization of a configurationally stable axially-chiral boramidine are reported, showcasing absorption in the UV domain, deep-blue fluorescence (Φ up to 94%), and ca. |10-3| gabs and glum values. Detailed photophysical studies and quantum-chemical calculations clearly elucidate the deactivation pathways of the emissive state to triplet excited states, involving increased spin-orbit coupling between the lowest singlet excited state and an upper triplet state.
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