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Updated: Jun 27, 2025

Atomically Traceable Nanostructure Fabrication
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Recent progress in atomically precise silver nanocluster-assembled materials.

Noohul Alam1, Anish Kumar Das1, Priyanka Chandrashekar1

  • 1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Thiruvananthapuram, Kerala, India 695551. sukhendu@iisertvm.ac.in.

Nanoscale
|May 7, 2024
PubMed
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Atomically precise silver nanoclusters (Ag NCs) are stabilized using nitrogen-based linkers to form advanced cluster-assembled materials (CAMs). These Ag(I)-based CAMs show great promise for applications in sensing, catalysis, and bio-imaging.

Area of Science:

  • Nanotechnology
  • Materials Science
  • Coordination Chemistry

Background:

  • Atomically precise silver nanoclusters (Ag NCs) possess unique properties but require stabilization.
  • Cluster-assembled materials (CAMs) offer enhanced stability and functionality by linking Ag NCs with organic molecules.
  • Nitrogen-based ligands are crucial for constructing stable Ag(I)-based CAMs.

Purpose of the Study:

  • To review the synthesis, structure-property relationships, and applications of atomically precise nitrogen-based ligand bonded Ag(I)-based CAMs.
  • To highlight advancements in integrating Ag(I) cluster nodes into periodic frameworks.
  • To explore the potential of Ag(I) CAMs in various technological fields.

Main Methods:

  • Review of recent literature on Ag(I)-based CAMs.

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  • Analysis of synthetic strategies for nitrogen-based ligand bonded Ag(I) clusters.
  • Examination of structure-property correlations in Ag(I) CAMs.

    • Main Results:

    • Nitrogen-based linkers enable the construction of stable, hierarchical Ag(I)-based CAMs.
    • Ag(I) CAMs exhibit tunable properties based on cluster node diversity and framework dimensionality.
    • These materials show significant potential in sensing, catalysis, bio-imaging, and device fabrication.

    Conclusions:

    • Ag(I)-based CAMs represent a significant advancement over individual Ag NCs.
    • The design of Ag(I) CAMs using nitrogen-based ligands offers a pathway to novel materials.
    • Further research into Ag(I) nanocluster assembly will drive innovation in advanced applications.