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Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
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Stretchable phosphorescent polymers by multiphase engineering.

Nan Gan1, Xin Zou1, Zhao Qian2

  • 1Frontiers Science Center for Flexible Electronics (FSCFE), MIIT Key Laboratory of Flexible Electronics (KLoFE), Northwestern Polytechnical University, Xi'an, 710072, China.

Nature Communications
|May 15, 2024
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Summary
This summary is machine-generated.

Researchers developed stretchable phosphorescent materials using multiphase engineering in block copolymers. These materials offer long-lived emission and high stretchability for advanced applications like wearable electronics and data encryption.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Optoelectronics

Background:

  • Stretchable phosphorescence materials are crucial for wearable electronics.
  • Balancing rigidity and flexibility for long-lived emission and high stretchability in polymers is a significant challenge.

Purpose of the Study:

  • To develop stretchable phosphorescent materials with simultaneously long-lived emission and high stretchability.
  • To explore multiphase engineering in block copolymers for advanced material properties.

Main Methods:

  • Multiphase engineering combining stiffness and softness in block copolymers.
  • Utilizing microphase separation to achieve desired material properties.
  • Demonstrating applicability across various binary and ternary initiator systems.

Main Results:

  • Achieved intrinsic stretchability up to 712% with an ultralong phosphorescence lifetime of 981.11 ms.
  • Developed color-tunable phosphorescence across the visible spectrum.
  • Enabled multi-level volumetric data encryption and stretchable afterglow displays.

Conclusions:

  • Multiphase engineering in block copolymers is an effective strategy for creating advanced stretchable phosphorescent materials.
  • The developed materials offer significant potential for wearable electronics, data encryption, and display technologies.
  • This work provides fundamental insights into designing stretchable materials with tunable optoelectronic properties.