Sustainable Zn²⁺ removal using highly efficient, novel, and cost-effective chitosan-magnetic biochar composite

This study focused on the development of a sustainable and low-cost adsorbent derived from the chitosan-biochar composite for the removal of Zn²⁺ from an aqueous solution. Biochar was prepared from cotton stalk residue by pyrolysis at 600 °C for 2 h, modified with FeCl_3, and composed with chitosan in various ratios (1:3, 1:1, 3:1), leading to the formation of an efficient, thermally stable, and rich with functional groups chitosan-biochar composite denoted as CHB-Fe-CS. Functional groups (hydroxyl, carboxyl, and amine) were identified as key contributors to the adsorption mechanism. Langmuir isotherm (R² = 0.99) and Pseudo-Second order (R² = 0.99) were best fitted models with the experimental results indicating chemisorption-driven monolayer adsorption. The results revealed CHB-Fe-CS (3:1) composite obtained the highest adsorption capacity of 117.50 mg/g for Zn²⁺ under optimal conditions viz., 180 min batch time, 500 mg/l metal concentration, 4 g/l adsorbent dosage, 40 °C solution temperature, and 5.0 pH. Regeneration of the used adsorbent was performed using 0.2 mol/l HCl and obtained desorption efficiency of 67.48% and 51.48% after the 4th and 8th cycles. The adsorption mechanisms were dominated by ion exchange, surface complexation, and electrostatic attraction compared to intra-particle diffusion and physisorption. The CHB-Fe-CS demonstrated an economical, environment friendly, and good performing adsorbent for water decontamination.