Efficient optimization of the synthetic conditions for aerosol-assisted high-quality mesoporous CeO₂ powders

The morphology of surfactant-assisted mesoporous metal oxides was tuned to obtain high surface-area particles by utilizing the synthetic conditions for fabricating transparent thin films through an evaporation-induced self-assembly (EISA) process. For investigating their potential applications, especially for designing heterogeneous catalysts, mesoporous metal oxides should be obtained in powder forms; however, a serious limitation associated with their reproducibility persists. Herein, along with a rapid optimization approach, starting from determining and improving chemical composition for the fabrication of mesoporous metal oxide films, an advanced approach to obtain highly porous metal oxide powders is presented using a temperature-controlled spray-drying process with step-by-step but smooth optimization by combining several EISA processes, involving the utilization of a precursor solution optimized for a slow-drying process in the case of ceria (CeO₂) using poly(styrene)-block-poly(ethylene oxide) (PS-b-PEO).